Dfs magnetic sector gchrms worldwide compliance setting the. The dfs has all the best performance of a magnetic sector ms. The direction of deflection of the ion beam is the same in both sectors. Double focusing in general is achieved when ions emerging. Dfs high resolution gcms high performance magnetic. Most modern sector instruments are doublefocusing instruments first developed by a. By considering the field angle and source location as independently variable, the analysis provides for an instrument more flexible in use than similar. A popular combination of these sectors has been the beb magnetic electric magnetic. The theta probe lens is unique because it can be operated in two modes. The single sector ms is made with a single magnetic analyzer. Miniature doublefocusing mass spectrometer design the design of the miniature mass analyzer is based on the mass separation and focusing capabilities of a 90 cylindrical doublefocusing mass analyzer using crossed electric and magnetic.
These studies, including ion structure determinations, were performed with use of double focusing mass spectrometers of both conventional and reversed geometry, and equipped with various types of metastable ion scanning and collision. The maldi leads to the sublimation and ionization of both the sample and matrix. Dec 20, 2004 an analysis is made of the focusing characteristics of a magnetic spectrometer having an annular magnetic field which varies approximately with 1r. A popular combination of these sectors has been the beb magneticelectricmagnetic. A high, medium, or low resolution setting for each method can automatically be selected for by using a switchable entrance slit.
Magnetic sector instruments are still used in cases where extremely high resolution is required such as double focusing instruments section 5. Further, the airsensitive 2ndgeneration hoveydagrubbs catalyst is analyzed by lifdims. It is the highest performance ms ever built for target compound analysis, and the first completely new double focusing instrument of its class in more than 15 years. Magnetic sector secondary ion mass spectrometry nist.
A double focusing electric sector magnetic box analyzer will be presented. Doublefocusing mass spectrometers combine magnetic and electric fields in various combinations, although the electric sector followed by the magnetic is more common. Since the ion paths through the magnetic sector are reversible, two ions of the same mass but different kinetic. Test of a miniature doublefocusing mass spectrometer for.
Double focusing mass analyzer, instrumentation of mass spectrometry, mass spectrometry, magnetic field deflection mass analyser, time of flight mass analyser, quadrupole mass analyser, dr. Summary of the characteristics of differ ent mass analyzers. Magnetic sector simion 2019 supplemental documentation. Double focusing magnetic sector field mass spectrometer ensures no signal loss from pulsing ions onto the analyzer and no scanning. Doublefocusing magnetic sector magnetic sector m q r2b2 2v b magnetic field strength r radius of curvature in magnetic field v accelerating voltage m ion mass q ion charge all ions of the same mz will have the same radius only if the ion kinetic energy is constant. These generated ions are separated depending on mz through a tof analyzer, and a spectral representation of these ions is generated and analyzed by the ms software, generating an ms profile. Fusing mass spectrometer technology from military and space applications, the mga iscan provides realtime multicomponent gas analysis. Arrangement of the electrostatic and magnetic sectors in the nier doublefocusing mass spectrometer. The various forces influencing the particle separate ions with different masstocharge ratios. Magnetic sector instruments are still used in cases where extremely high resolution is required such as doublefocusing instruments section 5. See also hemispherical deflection analyzer hda, which is combined with a magnetic sector in a double focusing magnetic sector.
Dec 08, 2014 types of mass analyzers quadrupole mass analyzer time of flight analyzer tof magnetic sector mass analyzer single focusing double focusing quadrupole ion trap mass analyzer ion cyclotron resonances 5. The ultra hrirms combines a 10 kv electron impact ionization source, a highmassresolution doublefocusing magneticsector mass analyzer, and a variable collector array for a resolving power of 18,000. Analyzer should consist of electrostatic analyzer and an electromagnet, which together can provide highresolution capability. High resolution allows the measurement of very accurate molecular masses, which leads to determination of exact chemical formula. Jeol usa mstation doublefocusing magnetic sector mass spec. It is perfectly double focusing, employing an ultrahigh precision toroidal electrostatic analyzer and a carefully refined magnetic analyzer. An electrostatic analyzer is added in this type of instrument to separate particles with difference in kinetic energies. High resolution mass spectrometer amd 604 s version 080321. It is characterized by a deflection angle and radius. As a result, many magnetic sector instruments have been replaced by quadrupole systems that are much smaller, lighter, and able to perform extremely fast scans. Amd analysis the innovators in magnetic sector mass. The spread in ionic energies produces a spread in their radii of curvature in the magnetic field. This directly translates into stability and ruggedness.
Its the first ion source used for mass spectrometry 1930. Newly developed compact magnetic sector mass spectrometer. High stability of the magnetic field 50 ppm or better is required. Like the magnetic sector, the electric sector applies a force perpendicular to the direction of ion motion, and therefore has the form of an arc. Part vi the mass analyzer part vii mass separation devices doublefocusing magneticsector technology part viii mass analyzers. It is the highest performance ms ever built for target compound analysis, and the first completely new double focusing instrument of its class in. Sector mass spectrometers have been used for the longest time 38. Since the ion paths through the magnetic sector are reversible, two ions of the same mass but different kinetic energies will be recombined at the detector slit. Hardware configurable to provide both continuous and instantaneous readings of gas concentrations with less than 1 second response time for all components.
By considering the field angle and source location as independently variable, the analysis provides for an instrument more flexible in use than similar existing. This magnetic sector analyzer is the first in its class with virtually no image aberrations. Mass measurement accuracy comparisons between a doublefocusing magnetic sector and a timeofflight mass analyzer article in rapid communications in mass spectrometry 2210. Single focusing magnetic sector mass spectrometer in a single focusing magnetic sector instrument there is a lack of uniformity of ion energies. For comparison with longestablished lifdi instrumentation, some of the spectra obtained with the new setup are also compared with those from a double focusing magnetic sector instrument. Double focusing magnetic sector mass analyzers are the classical model against which other. The mstation is capable of achieving a resolving power of 60,000 or greater at 10% valley. The magnetic analyzer separates ions of different mz into different beams by.
Instruments research resources center university of. Find double focussing mass spectrometers related suppliers, manufacturers, products and specifications on globalspec a trusted source of double focussing mass spectrometers information. Double focusing magnetic sector mass spectrometer of the new amd compact class in special eb configuration incorporating the unique amd quas 3 ar detector technology with simultaneous multichannel ion detection system. Multi collector magnetic sector inductively coupled plasma. The pb ions are analyzed using a double focusing mass spectrometer that comprises both an electrostatic and magnetic analyzer. The mga iscan system advances the stateoftheart in process mass spectrometry with the first double focusing, magnetic scanning process analyzer measuring from low ppb to 100%. For optimal stability and ruggedness, it is perfectly doublefocusing, with ultrahighprecision toroidal electrostatic and refined magnetic analyzers. A widely used variation of this is the double sector ms. The siemens fticr instrument achieves resolution beyond 400,000 and could possibly resolve the tritium ion from the helium3 ion, which differ by the weight more of an electron, 0. A magnetic sector is a type of mass analyzer using a static magnetic field to deflect particles in this way along a roughly circular arc. Even though this particular case has been adapted for a doublefocusing magnetic sector mass spectrometer, an ion of mz 100, and an acceleration voltage of 8 kv, the effective time scales for other types of beam instruments quadrupole, timeofflight. Offers worldwide full compliance with any official dioxin, pcb, or pbde method e.
A new mass spectrometer without a magnetic field journal. Based on magnetic sector technology, the dfs magnetic sector gchrms performs dioxin and pops routine analysis, delivering ultimate confidence, no matter the sample type or matrix. Mass analyzers mass spectrometry chemistry libretexts. For historical reasons, this is referred to as a reversegeometry magnetic sector mass.
Ical system logic for continuous optimal operation. The angle of the electrostatic sector is 90 and that of the magnetic sector 60. Magnetic and multielement electrostatic input lenses. Icp mass spectrometer for inorganic material analysis. For example, a well tuned double focusing magnetic sector instrument can have mass resolution in the range mdelta 500m to 10,000. The result is peak broadening and low to moderate mass resolution.
The paths are controlled by varying the strength of the magnetic field. Avantage software for data acquisition and analysis. Gc sample injection methods include manual syringe injection and solid phase microextraction spme fiber injection. After every cycle in a depth profile analysis, the software invokes an energy distribution measurement and. Magnet and esa are carefully chosen to match the energy focusing properties of one another and are arranged so that the direction of energy focusing is in opposite. A compact double focusing magnetic sector analyzer applying mattauchherzog ion optical geometry focal plane for the detection of highly resolved ions in a wide mass range at constant magnetic field. Dfs high resolution gcms high performance magnetic sector. Magnetic sector secondary ion mass spectrometry sims generates isotopic and elemental information from solid surfaces with depth profiling capabilities to measure the concentration of isotopes and elements as a function of depth into the film. For backgroundtheory, particularly on focusing properties in design, see 5 6 7. Classical and special amd magnetic sector mass spectrometers extracted from power point presentations. A compact double focusing magnetic sector analyzer applying. Conventional double focusing magnetic sector instruments have a resolution that is. Its design is based on the mass separation of a 90 magnetic sectorfield analyzer with a double trajectory, which has a magnetic induction of 0.
Selfsupplied liquid injection field desorptionionization. The mass analyzer is an electricmagneticelectric ebe sector a double focusing sector. The mga 1200ec process mass spectrometer is a fixed magnetic sector analyzer that provides rapid, accurate and stable realtime analysis of up to 15 gas components in multiple gas streams. Dfs magnetic sector gcms 2 dfs magnetic sector gcms the dfs is a high resolution magnetic sector mass spectrometer like none before.
However when both techniques are used together, it is called a double focusing instrument. Jeol gcmate ii double focusing magnetic sector gcms ei, ci, fab m. Also, due to the fact that ions have much larger masses than electrons, larger analyzer dimensions and deflection field strengths are used than for the energy analyzer. Escalab 250 is the instrument to use the same input lens and analyzer for both parallel imaging and spectroscopy. Double focusing magnetic sector analyzer was developed, in this instrument the dispersion of space and kinetic energy is reduced, giving better resolution of the mass spectra and also the possibility of tandem mass spectrometry. The thermo scientific dfs is a high resolution magnetic sector mass spectrometer like none before. The instrument can record mass range from 1 to 50 amu based on two. The ultra hrirms combines a 10 kv electron impact ionization source, a highmassresolution double focusing magnetic sector mass analyzer, and a variable collector array for a resolving power of 18,000. Conventional double focusing magnetic sector instruments have a resolution that is limited to about 5000.
Spectro ms is a doublefocusing sector field icp ms icp mass spectrometer based on a mattauchherzog geometry spectro ms is a doublefocusing sector field icp ms icp mass spectrometer based on a mattauchherzog geometry with a newly developed ion optic. The jeol gcmate ii is a high resolution double focusing magnetic sector benchtop gc mass spectrometer equipped with ion sources for electron impact ei, chemical ionization ci and fast atom bombardment fab by direct insertion probe and is capable of exact mass measurements for elemental composition determinations. These provides the high resolution to achieve better focusing, energy has to be reduced before ions are allowed to enter the magnetic field and increase resolving power can be obtained two mass analyzers in series. Mstation doublefocusing magnetic sector mass spectrometer the mstation is a fullyautomated, highperformance, doublefocusing magnetic sector mass spectrometer designed for highresolution gcms analyses. Compatible with epa, fda, clp and 21 cfr part 11 as well as other standards and guidelines. It has a 90 magnetic sectorfield analyzer with double trajectory, which has a magnetic flux density of 0.
If you are new to this topic, you may want to read up on the single sector mass spectrometer before continuing. The mga iscan system advances the stateoftheart in process mass spectrometry with the first doublefocusing, magnetic scanning process analyzer measuring from low ppb to 100%. Classical and special amd magnetic sector mass spectrometers. This earliest of hybridizations uses the electric sector to focus ions by their kinetic energy as they exit the source. Two special trajectories are selected to cover the mass ranges, 112 amu and 6. For comparison with longestablished lifdi instrumentation, some of the spectra obtained with the new setup are also compared with those from a doublefocusing magnetic sector instrument. Mass analyzer and detector the magnetic sector analyzer is the first with virtually no image peculiarities. For backgroundtheory, particularly on focusing properties in design, see. The mstation is a fullyautomated, highperformance, doublefocusing magnetic sector mass spectrometer designed for highresolution gcms analyses. In a doublefocusing mass analyzer beam is first passes radial electrostatic field. Mass measurement accuracy comparisons between a double. Mga iscan mass spectrometer with doublefocusing, magnetic.
Intuitive instrument software allows control of the entire ion optic. The esa should be stable within better than 50 ppmh. Double focusing magnetic sector magnetic sector m q r2b2 2v b magnetic field strength r radius of curvature in magnetic field v accelerating voltage m ion mass q ion charge all ions of the same mz will have the same radius only if the ion kinetic energy is constant. The ion optics are robust, yet they enable high sensitivity, selectivity, and. A schematic representation of the jeol mstation double focusing mass spectrometer is shown below. Doublefocusing mass spectrometer mass spectrometry terms. Details of the configuration of the mass spectrometer vary from one application to another, but all utilize both magnetic and electrostatic analyzers, commonly referred to as sectors. In this paper, a novel compact magnetic sector mass spectrometer has been developed and tested at the lanzhou institute of physics.
Electrostatic and magnetic sector analyzers when employed individually are single focusing instruments. A circular beam path of 180, 90, or 60 degrees can be used. Summary of the characteristics of differ ent mass analyzers all mass spectrometers combine ion formation, mass analysis, and ion detection. Analyzer the newly designed dfs analyzer has virtually no image aberrations. Double focusing mass spectrometers combine magnetic and electric fields in various combinations, although the electric sector followed by the magnetic is more common. If the electrostatic analyzer sector precedes the magnetic sector, the design is referred to as forward geometry. A sector instrument is a general term for a class of mass spectrometer that uses a static electric or magnetic sector or some combination of the two separately in space as a mass analyzer. Jun 17, 2019 the single sector ms is made with a single magnetic analyzer.
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